7.57 Spills of organic chemicals that contact the ground sometimes reach the
groundwater table, where they are then carried downgradient with the groundwater flow.
The rate at which they are transported with the groundwater is decreased by sorption to
the solids in the groundwater aquifer. The contaminated groundwater can reach wells,
which is dangerous if the water is used for drinking. (a) For a soil having ρb of 2.3 g/cm3
and a porosity of 0.3, and for which the percent organic carbon equals 2 percent,
determine the retardation factors of trichloroethylene
,
hexachlorobenzene
, and dichloromethane
. (b) Which
compound would be transported farthest, second farthest, and least far with the
groundwater if these chemicals entered the same aquifer?
Solution:
a. You will use equation 7.23 to solve for the retardation factor, Rf. However, first you