
4.27 The concentration of a pollutant along a quiescent water-containing tube is shown in Figure
4.28. The diffusion coefficient for this pollutant in water is equal to 10-5 cm2/s. (a) What is the
initial pollutant flux density in the x–direction at the following locations: x = 0.5, 1.5, 2.5, 3.5,
and 4.5? (b) If the diameter of the tube is 3 cm, what is the initial flux of pollutant mass in the x–
direction at the same locations? (c) As time passes, this diffusive flux will change the shape of
the concentration profile. Draw a sketch of concentration in the tube versus x–axis location
showing what the shape at a later time might look like. (It is not necessary to do any calculations
to draw this sketch.) Assume that the concentration at x = 0 is held at 3 mg/L and the
concentration at x = 6 is held at 1 mg/L. (d) Describe, in one paragraph, why the concentration
profile changed in the way that you sketched in your solution to part (c).
Solution: