1
6.40 The following are measurements of the rate coefficient, k, for the reaction at
different temperatures, T:
(a) Use the method of least-squares to bes t fit a function of the form to the data.
Determine the constants C, b, and D by curve fitting a linear combination of the functions ,
, and to the given data (Section 6.8).
(b) Usually, the rate coef ficient is express ed in the form of an Arrhenius equation ,
where A and b are constants, J/mole/K is the universal gas constant, and is the activation
energy for the reaction. Having determined the constants C, b, and D in part (a), deduce the values of A
(m3/s) and (J/mole) in the Arrhenius expression.
Solution
(a) Using Eq. (6.97), the following system of three linear equations for the unknowns C, b, and D can be
written:
T (K) 595 623 761 849 989 1076 1146 1202 1382 1445 1562
(m3/s) 2.12 3.12 14.4 30.6 80.3 131 186 240 489 604 868
k()ln Cb T()ln D
T
—–
–+=