1
5.6 The structure of an BeCl2 molecule may be idealized as three
masses connected by two springs, where the masses are the beryllium
and chlorine atoms, and the springs represent the chemical bond
between the beryllium and chlorine atoms.The equation of motion for
each atom (mass) may be written as:
where k is the restoring force spring constant representing the Be–Cl bonds. Since the molecule is free to
vibrate, normal mode (i.e., along the axis) vibrations can be examined by substituting , where
is the amplitude of the jth mass, , is the frequency, and t is time. This results in the following
system of equations:
(5.57)
(a) Rewrite the system of equations in Eq. (5.57) as an eigenvalue problem, and show that the quantity
is the eigenvalue.
(b) Write the characteristic equation and solve for the different frequencies when kg/
s2, kg, and kg.
(c) Find the wavelengths (where m/s is the speed of light in vacuum) that corre-
spond to the frequencies from part (b). Express the answers in units of microns or m (where
m).
(d) Determine the eigenvectors corresponding to the eigenvalues found in part (c). From the eigenvectors,
deduce the relative motion of the atoms (i.e., are they moving toward or away from each other?)
Solution
(a) The system of equations (5.57) can be re-written in the following matrix form:
Be Cl
Cl
x2x3
x1
mCl mCl
mBe
mCl
d2x1
dt2
———– kx1
–kx2
+=
mBe
d2x2
dt2
———– 2kx2
–kx1kx3
++=
mCl
d2x3
dt2
———– kx2kx3
–=
ω2A1
–k
mCl
——-– A1
–k
mCl
——-– A2
+=
ω2A2
–2k
mBe
——––A2
–k
mBe
——––A1
k
mBe
——––A3
++=
ω2A3
–k
mCl
——-– A2
k
mCl
——-– A3
–=
mCl 35.45 1.6605 10 27–
××=
mBe 9.01 1.6605×10 27–
×=