PROBLEM 10.3
KNOWN: Spherical bubble of pure saturated vapor in mechanical and thermal equilibrium with its
liquid.
FIND: (a) Expression for the bubble radius, (b) Bubble vapor and liquid states on a p-v diagram; how
changes in these conditions cause bubble to collapse or grow, and (c) Bubble size for specified
conditions.
SCHEMATIC:
ASSUMPTIONS: (1) Liquid-vapor medium, (2) Thermal and mechanical equilibrium.
373.15K): psat = 1.0133 bar, s = 58.9 × 10-3 N/m.
ANALYSIS: (a) For mechanical equilibrium, the difference in pressure between the vapor inside the
bubble and the liquid outside the bubble will be offset by the surface tension of the liquid-vapor
interface. The force balance follows from the free–body diagram shown above (right),
Thermal equilibrium requires that the temperatures of the vapor and liquid be equal. Since the vapor
inside the bubble is saturated, pi = psat,v (T). Since po < pi, it follows that the liquid outside the
bubble must be superheated; hence, po =
(T), the pressure of superheated liquid at T. Hence, we
can write,
(b) The vapor [1] and liquid [2] states are represented on the following p-v diagram. Thermal
equilibrium requires both the vapor and liquid to be at the same temperature [3]. But mechanical
equilibrium requires that the outside liquid pressure be less than the inside vapor pressure [4]. Hence
the liquid must be in a superheated state. That is, its saturation temperature, Tsat(po) [5] is less than
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