Chemistry Chapter 5 2 Symmetry And Chirality section 6difficulty Hard83 Draw All

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subject Pages 9
subject Words 944
subject Textbook Organic Chemistry 1st Edition
subject Authors David R. Klein
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58. What is the % of the S enantiomer in a sample of carvone that has a specific
rotation of -20, given that the specific rotation of R-carvone is -61?
59. What is the relationship of the following two structures?
OH
NH
OH
NH
A. Enantiomers
B. Diastereomers
C. Constitutional Isomers
D. Identical
60. What is the relationship of the following two structures?
OH
NH
OH
NH
A. Enantiomers
B. Diastereomers
C. Constitutional Isomers
D. Identical
61. What is the relationship of the following two structures?
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OO
HO OH
HO
OO
HO OH
HO
A. Enantiomers
B. Diastereomers
C. Constitutional Isomers
D. Identical
62. What is the relationship of the following two structures?
O
HO OH
OO
HO OH
HO
OH
O
A. Enantiomers
B. Diastereomers
C. Constitutional Isomers
D. Identical
63. What is the relationship of the following two structures?
OO
HO OH
HO
OO
HO OH
HO
A. Enantiomers
B. Diastereomers
C. Constitutional Isomers
D. Identical
64. Draw the enantiomer of the following compound.
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65. Draw the enantiomer of the following compound.
HO OH
OH
66. Draw the enantiomer of the following compound.
67. Draw a diastereomer of the following compound.
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68. Draw a diastereomer of the following compound.
OH
69. Draw a diastereomer of the following compound.
OH
OH
70. Provide all the stereoisomers of the following compound.
71. Provide all the stereoisomers of the following compound.
OH
NH
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72. Which of the following is a diastereomer of the following compound.
OH
NH NH
OH
NH2
OH
NH
OH
NHA. B. C. D.
73. Which of the following is a diastereomer of the following compound.
O O
O
O
O
A. B. C. D.
74. Which of the following is a diastereomer of the following compound.
Cl
Cl
Cl Cl Cl
Cl Cl
Cl Cl
A. B. C. D.
75. Is the following a meso compound?
Cl
Cl
76. Which of the following can have a meso isomer?
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Cl Cl
Br Cl
Br
A. B. C. D.
77. Does the following contain a plane of symmetry?
78. Draw in the plane of symmetry in the following compound.
79. Draw in the plane of symmetry in the following compound.
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80. Draw in the plane of symmetry in the following compound.
81. Draw all of the possible stereoisomers for the following compound.
82. How many stereoisomers are possible for 2,3-dimethylbutane?
83. Draw all possible stereoisomers of 1,3,5-trichlorocyclohexane.
84. Draw the meso isomer of the following compound.
Cl Cl
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85. Draw the meso isomer of the following compound.
MeO2CCO2Me
OH
86. Draw the meso isomer of the following compound.
OH
OH
87. Convert the following structure into a Fischer projection.
Br
Br
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88. Convert the following structure into a Fischer projection.
MeO2CCO2Me
OH
89. Convert the following structure into a Fischer projection.
OH
OH
OH
OH
90. Convert the following structure into a Fischer projection.
OH
OH
OH
OH
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91. Convert the following Fischer projection into a wedge/dash drawing.
H OH
HO H
92. Convert the following Fischer projection into a wedge/dash drawing.
HO H
HO H
H OH
93. Convert the following Fischer projection into a wedge/dash drawing.
HO H
HO H
HO H
H OH
94. Convert the following Fischer projection into a wedge/dash drawing.
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OH
H
HO H
95. Which of the following is the correct Fischer projection of the following
compound?
Br
Br
H Br
Br H
Br H
H Br
H Br
H Br
Br H
Br H
A. B. C. D.
96. Which of the following is the correct Fischer projection of the following
compound?
Br
Br Et
H Br
Br H
Et
H Br
Br H
Et
H Br
H Br
Et
Br H
Br H
A. B. C. D.
97. Which of the following is the correct Fischer projection of the following
compound?
OH
OH
OH
OH
HO H
H OH
HO H
HO H
HO H
H OH
HO H
H OH
H OH
H OH
H OH
HO H
H OH
H OH
H OH
H OH
A. B. C. D.
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98. Which of the following structures is the correct wedge/dash drawing of the
following Fischer projection?
Br H
Br H Br
Br
Br
Br
Br
Br
Br
Br
A. B. C. D.
99. Which of the following structures is the correct wedge/dash drawing of the
following Fischer projection?
Et
H Br
Br H
Br
Br
Br
Br
Br
Br
Br
Br
A. B. C. D.
100. Which of the following structures is the correct wedge/dash drawing of the
following Fischer projection?
H OH
H OH
H OH
H OH
OH
OH
OH
OH OH
OH
OH
OH OH
OH
OH
OH OH
OH
OH
OH
A. B. C. D.
101. What is the relationship between the following two molecules?
Et
H Br
H Br
Et
Br H
Br H
A. Enantiomers
B. Diastereomers
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C. Identical
D. Constitutional Isomers
102. What is the relationship between the following two molecules?
HO H
H OH
HO H
H OH
H OH
H OH
H OH
HO H
A. Enantiomers
B. Diastereomers
C. Identical
D. Constitutional Isomers
103. What is the relationship between the following two molecules?
Br
Br
H Br
Br H
A. Enantiomers
B. Diastereomers
C. Identical
D. Constitutional Isomers
104. Assign the following stereocenter as R or S.
OH
H Et
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105. Assign the following stereocenter as R or S.
H
HO H
106. Assign the following stereocenter as R or S.
Et
H Br
H H
107. Provide an IUPAC name for the following compound.
OH
H Et
108. Which of the following is the IUPAC name for the following compound.
OH
H Et
A. (S)-2-pentanol
B. (S)-2-butanol
C. (R)-2-pentanol
D. (R)-2-butanol

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