81) Two experimental runs are performed to determine the calorimetric properties of an alcohol
which has a melting point of -10.0° C. In the first run, a 200-g cube of frozen alcohol, at the
melting point, is added to 300 g of water at 20.0°C in a styrofoam container. When thermal
equilibrium is reached, the alcohol-water solution is at a temperature of 5.0°C. In the second run,
an identical cube of alcohol is added to 500 g of water at 20.0°C and the temperature at thermal
equilibrium is 10.0°C. The specific heat capacity of water is 4190 J/kg ∙ K. Assume no heat is
exchanged with the styrofoam container and the surroundings. What is the heat of fusion of the
alcohol?
A) 5.5 × 104 J/kg
B) 6.3 × 104 J/kg
C) 7.1 × 104 J/kg
D) 7.9 × 104 J/kg
E) 8.7 × 104 J/kg
82) Two experimental runs are performed to determine the calorimetric properties of an alcohol
which has a melting point of -10° C. In the first run, a 200-g cube of frozen alcohol, at the
melting point, is added to 300 g of water at 20°C in a styrofoam container. When thermal
equilibrium is reached, the alcohol-water solution is at a temperature of 5°C. In the second run,
an identical cube of alcohol is added to 500 g of water at 20°C and the temperature at thermal
equilibrium is 10°C. The specific heat capacity of water is 4190 J/kg ∙ K. Assume no heat is
exchanged with the styrofoam container and the surroundings. What is the specific heat capacity
of the alcohol?
A) 1700 J/kg ∙ K
B) 1900 J/kg ∙ K
C) 2100 J/kg ∙ K
D) 2300 J/kg ∙ K
E) 2500 J/kg ∙ K
83) How many grams of ice at -17°C must be added to 741 grams of water that is initially at a
temperature of to produce water at a final temperature of Assume that no heat is lost to
the surroundings and that the container has negligible mass. The specific heat of liquid water is
4190 J/kg ∙ C° and of ice is 2000 J/kg ∙ C°. For water the normal melting point is 0°C and the
heat of fusion is 334 × 103 J/kg. The normal boiling point is 100°C and the heat of vaporization
is 2.256 × 106 J/kg.