Phases and Composition of Matter
What is Chemistry?
Chemistry is the science that seeks to understand what matter does by studying what
atoms and molecules do.
What is Matter?
Matter can be classified as solid, liquid, or gas based on what properties it exhibits.
Scientific Method
A process for trying to understand nature by observing nature and the way it behaves,
and by conducting experiments to test our ideas.
Key characteristics of the scientific method include Observation, formulation of
Hypotheses, Experimentation, and formulation of Laws and Theories.
Phases of Matter
Solid matter may be crystallinein which case its atoms or molecules are in patterns
with long-range, repeating order. Others may be amorphous, in which case its atoms or
molecules do not have any long-range order.
In liquid matter, atoms or molecules pack about as closely as they do in solid matter, but
they are free to move relative to
each other.
In gaseous matter, atoms or molecules have a lot of space between them.
Phase Changes
Composition of Matter
Physical Properties: Separation Techniques
Decantation is a process for the separation of mixtures of immiscible liquids or of a
liquid and a solid mixture such as a suspension.
Distillation is the process of separating the components or substances from a liquid
mixture by using selective boiling and condensation.
Chromatography: the separation of a mixture by passing it in solution or suspension or
as a vapor (as in gas chromatography) through a medium in which the components
move at different rates
Evaporation: a technique used to separate out homogenous mixtures where there is
one or more dissolved solids, used primarily to drive off the liquid components from the
solid components
Filtration is the process of separating suspended solid matter from a liquid, by causing
the latter to pass through the pores of some substance, called a filter. The liquid which
has passed through the filter is called the filtrate.
Chemical and Physical Properties
A chemical property
is a property that a substance displays
only by changing its composition via a chemical change (or chemical reaction).
The flammability of gasoline, in contrast, is a chemical property.
Chemical properties include corrosiveness, acidity, and toxicity.
A physical property is a property that a substance displays without changing its
composition.
Odor, taste, color, appearance, melting point, boiling point, and density are all
physical properties.
Physical properties can be broken down into two categories:
1. Extensive Properties- Depends on the amount of matter in a sample.
Examples
Mass/Weight of a sample
Volume/Capacity of a sample
Length/Distance of a sample
Temperature of a sample
2. Intensive Properties- Independent of the amount of matter in a sample.
Focuses on observable characteristics.
Examples
Color, odor, luster
Hardness, density, specific gravity
Melting point, freezing point, boiling point
Malleability, ductility, conductivity
Physical and Chemical Changes
Physical changes are changes that alter only the state or appearance, but not
composition. (The atoms or molecules that compose a substance do not change their
identity during a physical change.) water boils to water vapor
Chemical changes are changes that alter the composition of the matter. (During a
chemical change, atoms rearrange, transforming the original substances into different
substances.) rusting of an iron nail
Measurements, Sig Figs, Scientific Notation
Metric and Customary Measurements
Metric system, used in most of the world
English system, used in the United States
Metric Conversions (Kilo to Milli)
Scientific Notation vs Standard Notation
When the exponent on 10 is positive, it means the number is that many powers of 10
larger. Example: Sun’s diameter = 1.392 x 109 m = 1,392,000,000 m.
When the exponent on 10 is negative, it means the number is that many powers of 10
smaller. Example: Average atom’s diameter = 3 x 1010 m = 0.0000000003 m.
Accuracy and Precision
Accuracy refers to how close the measured value is to the actual value.
Precision refers to how close a series of measurements are to one another or how
reproducible they are.
Significant Digits
First, ALL digits 1-9 ARE SIGNIFICANT
Sandwiched zeros: these ARE SIGNIFICANT digits
Trailing zeros BEFORE decimal point: NOT SIGNIFICANT, unless they are followed by a
decimal point.
Trailing zeros AFTER decimal point: SIGNIFICANT
Leading zeros before and after a decimal point are NOT SIGNIFICANT
Calculations using Significant Digits
Addition/Subtraction
10.44 17.3355 11.2 1000
+ 1.0771 3.4 – 9.9345 + 2.11
11.5171 13.9355 1.2655 1002.11
11.52 13.9 1.3 1002 (Rounded to sig fig)
Multiplication/Division
3.50 x 1.4500 = 5.075 5.07 (3 sig figs)
1.77 / 0.50 = 3.54 3.5 (2 sig figs)
1441 x 3.03 = 4366.23 4370 (4 sig figs)
1000 / 2.11 = 473.9336 500 (1 sig figs)
Unit Conversions and Density
Dimension Analysis Conversions
Conversions of multiple steps
Conversions of units raised to a power
Conversions of rates (multi units)
Density
Definition of Density- The amount of mass in a given unit of volume. Expressed as a
ratio of mass over volume.
Finding density of geometric shapes- Calculate using formulas for materials that have
shapes similar to geometric figures.
Cube: V=lwh
Cylinder: V=𝜋r2h
Cone: V=1
3 𝜋r2h
Sphere: V=4
3 𝜋r2h
Finding density of irregular shapes
1. Fill graduated cylinder approx. ½ full of water
2. Record initial volume of water
3. Carefully place object into graduated cylinder